[ENER] New Process Could Help Make Hydrogen Fuel Affordable

rb.

Membership Revoked
http://news.nationalgeographic.com/news/2004/08/0827_040827_hydrogen_energy.html

New Process Could Help Make Hydrogen Fuel Affordable


Stephanie Peatling in Sydney
for National Geographic News
August 27, 2004


Scientists in Australia say they have have made a breakthrough in the efficiency of using sunlight to generate hydrogen from water. It may be a step toward an affordable source of clean energy.

A renewable source of energy to replace the world's declining fossil fuel reserves is perhaps the scientific community's holy grail. Hydrogen is all around us. It is seen by many as the cleanest and most efficient fuel for powering everything from vehicles to furnaces and air-conditioning—if only we can find an affordable way to harness it.

Now two researchers in Australia say they have made substantial progress.

Scientists have known for a long time how to split water into its two elements, oxygen and hydrogen. But the problem is that the process requires electricity—typically derived from fossil fuels—which makes the process counterproductive and expensive.

Janusz Nowotny and Charles Sorrell are researchers from the Centre for Materials Research in Energy Conversion at the University of New South Wales in Sydney, Australia. They have been looking for an economical way to use titanium dioxide to act as a catalyst to split water into oxygen and hydrogen—using solar energy.

The Stuff of Toothpaste

Titanium dioxide (TiO2) is widely used as a white pigment in paint, paper, cosmetics, sunscreens, and toothpastes. It is found in its purest form in rutile, a beach sand but is also extracted from certain ores. Rio Tinto, a mining company that produces titanium oxide, helps fund Nowotny's and Sorrell's research.

Nowotny and Sorrell announced their breakthrough today at the International Conference on Materials for Hydrogen Energy, hosted by the University of New South Wales in Sydney. They believe they have found a way to considerably improve the productivity of the solar hydrogen process (using sunlight to extract hydrogen from water) using a device made out of titanium dioxide.

"This is potentially huge, with a market the size of all the existing markets for coal, oil, and gas combined,'' Nowotny said in a news statement released ahead of the conference. "Based on our research results, we know we are on the right track."

Although Australia's sunny climate makes it an ideal place to generate solar energy, Sorrell said the technology could be used anywhere in the world.

"It's been the dream of many people for a long time to develop it, and it's exciting to know it's within such close reach," Sorrell said.

Honda-Fujishima Effect

The Australians' research has not been tested yet by other scientists, although the findings were applauded by the pioneers of the solar hydrogen process, Akira Fujishima and Kenichi Honda.

In 1967 the Japanese scientists discovered that titanium dioxide could be used to extract hydrogen from water in a process that has become known as the Honda-Fujishima effect. The finding was reported in the journal Nature and led to numerous awards, including the 2004 Japan Prize in the category Chemical Technology for the Environment.

Hydrogen is "very simple but very efficient,'' said Fujishima, who is also in Sydney for today's conference. "We must keep working hard on it.''

Since the 1967 discovery much research has focused on the materials that might be used to split water with sunlight.

Fujishima, chairman of the Kanagawa Academy of Science and Technology, says using titanium dioxide as a catalyst means energy production will result in "cleaner air, cleaner water, and a cleaner atmosphere."

Many Years to Hydrogen Power

The world is still a long way off from large-scale conversion from fossil fuels to hydrogen for its energy needs. For one thing, the Honda-Fujishima effect, even if it is greatly enhanced by the research breakthrough announced today, still has to be adapted into devices that can be used on a commercially viable scale. Engineers will have to design fuel cells that collect sunlight from rooftops and elsewhere.

The world's energy infrastructure is primarily based on fossil fuels and nuclear energy. Transitioning from gasoline-powered vehicles and gas stations to hydrogen-fuel replacements would require a huge investment and many years. Storage and safety issues still need to be resolved.

But the vision of a world powered by hydrogen is gaining momentum and science and technology is catching up.

T. Nejat Veziroglu is the director of the Clean Energy Research Institute at the University of Miami and the president of the International Association for Hydrogen Energy. He was called a "hydrogen romantic'" when he first started talking about a world powered by hydrogen in the 1960s.

Veziroglu recently appeared before a U.S. Congressional hearing. Afterward, he said, he was stopped by a committee member who told him hydrogen would never be as cheap as existing forms of energy. "I said, make the companies responsible for environmental damage and no one will use anything but hydrogen. That way the whole world will benefit.''
 

calliope

Contributing Member
Scientific American Frontiers with Alan Alda ran a program last May about a Iceland inventor, Stanley Ovshinsky, who has developed a solid state material that soaks up hydrogen like a sponge for gas tanks to power hydrogen vehicles. Not only a safe way to use and transport hydrogen, but your gas tank will even protect you in a crash. Iceland can make hydrogen with geothermal energy. Build the hydrogen stations right over the vent and make the hydrogen on site. Think they said their goal was to make Iceland that now imports almost all its fuel a total hydrogen economy by 2010 then look to exporting it to other countries. Here is a link to the transcript. You can also watch the segment on line.

http://www.pbs.org/saf/1403/resources/transcript.htm#3
 

Jef

Membership Revoked
Associated Press
UPS to Use Hydrogen Fuel Cells on Trucks
08.27.2004, 05:31 AM

United Parcel Service will begin using three large package delivery vehicles powered by hydrogen fuel cells, and officials said the goal is to someday apply the technology throughout its entire fleet.

The Dodge Sprinter trucks are being deployed in Ann Arbor, Mich., and two California locations: Los Angeles and Sacramento, UPS senior vice president of global transportation services said Thursday.

"Shifting away from a fossil-fuel based economy to a hydrogen economy would be a great environmental and technological achievement," Mahoney said at a Los Angeles news conference, where he was joined by representatives from DaimlerChrysler, the U.S. Environmental Protection Agency, the Department of Energy and the state of California.

Atlanta-based UPS was encouraged by results of tests on vehicles using hydrogen fuel cells.

Starting in March, DaimlerChrysler provided an "F-Cell," a fuel cell-powered Mercedes-Benz A-Class car, which UPS modified for early morning package deliveries in southeastern Michigan. The car is fueled daily at the EPA's hydrogen fueling station at its National Emissions Testing Laboratory in Ann Arbor.

"UPS now is jumping from a small fuel cell car to a medium-duty truck. We will continue the rapid application of this technology in hopes that in the near future, we can deploy zero-emission engines across our fleet of 88,000 vehicles," he said.
 

BH

. . . .
A new conversion process is necessary before H can be viable. My main concern is does the water used in the conversion need to be pure and clean.

If so, pure and clean water is already a concern to the planet. If not, will the polluted residues from the splitting of polluted water become another environmental/hazardous waste issue.
 

bw

Fringe Ranger
"If not, will the polluted residues from the splitting of polluted water become another environmental/hazardous waste issue."

If the hydrogen is extracted, you have the oxygen and pollutants left. The oxygen might combine with the pollutants, or (if the oxygen comes off as a gas) you might just have the pollutants. In effect, you are purifying the water as you break the molecules, leaving the crud. You aren't generating more crud, but reducing the volume and removing the water from the crud you have.

In other words, maybe this is a way to handle contaminated water of any kind - boil off the gases and then decide how to dispose of the residue depending on what kind of nasty it was. If that's the case, then you don't want to do the process with clean water at all, but with the dirtiest water you can find.

Hmm.

bw
 

Rob

Inactive
Sounds good but I'm always leery of power developed from chemical change because we don't know the long range effects from something as innocuous as water. We are talking about changing the atmospheric relationship of the elements back and forth if we do this large scale.
Now before we’ve started we can already see that there will be ‘sludge’ from the impurities in the water. Yes, I know this is in the environment already but now we will be condensing it. No one is going to want it in their back yard. These types of problems are unavoidable when you have chemical changes.
Nobody thought 50 years ago that car exhausts would be anything to worry about. Now look what we have.
If we can use it short term until we develop better solar then ok but look around at all the wind and solar we can have right now and we could use wind to built solar panels so no fossel fuels would be needed in the process.
I'm eager to see things like the new panels from ST micro before I start getting into hydro, just my opinion.
 

Aleph Null

Membership Revoked
Interesting article, no real details unfortunately. Seem to be lots of people trying to find the "magic bullet" with hydrogen; most do not pan out.

-A0-
 

Oilpatch Hand

3-Bomb General, TB2K Army
Storage and safety issues still need to be resolved.

Yes...even if the hydrogen-from-water process ever achieves an EROEI ratio of 1.00 or greater (highly doubtful), then we still have the problem of storing the hydrogen. Due to its tiny molecular size, hydrogen permeates any and all containers used to store or transport it. While there are prototypes of hydrogen storage tanks today, said vessels have to outweigh their contents by many hundreds of times in order to completely contain a very limited amount of gas.

This doesn't bode well for hydrogen's prospects as a transportation fuel, at least for motor vehicles.
 
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